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AISI 316 1.4401 VS AISI 316L 1.4404 Stainless steel

Below is a detailed comparative analysis of AISI 316, AISI 316L, 1.4404 and 1.4401 stainless steels:

1. Standard Equivalents

Standard System Grade Description
European (EN) 1.4401 Equivalent to AISI 316, C ≤0.07%
European (EN) 1.4404 Equivalent to AISI 316L, extra-low carbon (C ≤0.03%)
American (AISI) 316 Austenitic stainless steel with Mo, better corrosion resistance than 304
American (AISI) 316L Extra-low carbon version of 316, weldable without post-weld annealing

2. Chemical Composition

Element 1.4401 / AISI 316 (%) 1.4404 / AISI 316L (%) Notes
C ≤0.07 ≤0.03 Lower carbon reduces intergranular corrosion risk
Cr 16.5–18.5 16.5–18.5 Forms passive film for corrosion resistance
Ni 10.0–13.0 10.0–13.0 Stabilizes austenite structure
Mo 2.00–2.50 2.00–2.50 Improves pitting and crevice corrosion resistance
Mn ≤2.00 ≤2.00 Enhances machinability
Si ≤1.00 ≤1.00 Deoxidizer for casting properties

3. Physical Properties

Property Value Unit Condition
Density 7.9–8.0 g/cm³ 20°C
Melting Point 1370–1450 °C -
Thermal Conductivity 15 W/(m·K) 20°C
Linear Expansion 16.5×10⁻⁶ 1/°C 20–100°C avg.
Electrical Resistivity 0.75×10⁻⁶ Ω·m 20°C
Elastic Modulus 193–200 GPa 20°C

4. Mechanical Properties (Annealed Condition)

Property 1.4401 / AISI 316 1.4404 / AISI 316L Unit
Yield Strength (Rp0.2) ≥200 ≥200 MPa
Tensile Strength (Rm) 500–700 500–700 MPa
Elongation (A5) ≥40% (thick)/≥30% (thin) ≥40% (thick)/≥30% (thin) %
Hardness ≤215 HB ≤215 HB -

Key Notes:
316L/1.4404 has lower carbon content than 316/1.4401, making it more suitable for welded applications where post-weld annealing is impractical.
Molybdenum (Mo) in both grades enhances resistance to chloride-induced corrosion (e.g., in marine or chemical environments).
Both grades are non-magnetic in the annealed state. 

Differences and selections:
316L/1.4404: Ultra-low carbon, no annealing required after welding to resist intergranular corrosion, suitable for welded structures (such as thick plates, complex parts).
316/1.4401: Slightly lower cost, suitable for non-welding or simple welding scenarios.
Corrosion resistance:
Stress corrosion may occur at high temperatures (>60°C) or in high-concentration chloride environments, and long-term exposure should be avoided.
Molybdenum content improves pitting resistance, but has limited resistance to high-concentration sulfuric acid and hydrochloric acid.
Weldability:
316L does not require annealing after welding, while 316 thick sections require annealing.
316L welding wire (such as ER316L) is recommended to match the low-carbon characteristics.

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